Semiconductor device and manufacturing method of the same

ABSTRACT

A semiconductor device and manufacturing method of the same is provided in which the driving current of a pMOSFET is increased, through a scheme formed easily using an existing silicon process. A pMOSFET is formed with a channel in a &lt;100&gt; direction on a (100) silicon substrate. A compressive stress is applied in a direction perpendicular to the channel by an STI.

CROSS-REFERENCE TO RELATED APPLICATION

The present application claims priority from Japanese patent applicationNo. JP 2006-159239 filed on Jun. 8, 2006, the content of which is herebyincorporated by reference into this application.

TECHNICAL FIELD OF THE INVENTION

The present invention relates to a semiconductor device and itsmanufacturing method and, particularly, to a semiconductor device inwhich the mobility of a field-effect transistor is improved, and itsmanufacturing method.

BACKGROUND OF THE INVENTION

LSI (Large Scale Integration) technology using silicon is anindispensable technology in modern society. For example, LSIs aremounted on personal computers and cellular phones. LSIs includesomething called a processor that processes information, such as a CPU(Central Processing Unit). To process more information, informationprocessing has to proceed faster. Enhancement of device performance hasbeen made so far mainly through device microfabrication. That is, theperformance of transistors is increased through microfabrication of eachtransistor that processes information, thereby making it possible tooperate at higher speeds. Performance enhancement through devicemicrofabrication in this manner is called scaling, which has become aleading principle supporting the semiconductor industry.

However, with minimum processing dimension at a manufacturing levelbecoming less than 100 nm, a significant difficulty has occurs tofurther device microfabrication. For example, each transistor supportinga CPU is mainly a Metal Oxide Semiconductor Field Effect Transistor, andthe film thickness of a gate insulating film of the MISFET is less than2.0 nm. This is as thin as approximately ten atom layers. If the film ismade to be thinner, a tunnel current flows directly through the gateinsulating film, and a power consumption increases.

To solve this problem, research and development of ahigh-dielectric-constant gate insulating film with dielectric constanthigher than that of conventional SiO₂ (since a relative dielectricconstant is often represented by k, this gate insulating film isreferred to as a high-k film) has been actively performed around theworld. It has been demonstrated that the tunnel current can be directlysuppressed indeed by applying a high-k film to the gate insulating filmof a transistor. However, it has been revealed that the mobility of achannel portion of the transistor (a region where a current flows in anON state) is decreased with the use of a high-k film. The mobilityrepresents a moving speed of a carrier in unit electric field, and itsunit is cm²/Vs. As is evident from the definition, a decrease inmobility causes deterioration of operation speed of the transistor. Thisis a critical defect in achieving performance enhancement of thetransistor.

As described above, an object of scaling the transistor is to processmore information at higher speed. However, if the mobility is decreasedat the risk of introducing a new material, that is, a high-k film, and aprocessing speed is decreased, this is a case of the tail wagging thedog. Therefore, although there are needs in industries desiring tointroducing a high-k film in view of power consumption, application of ahigh-k film to a gate insulating film has not yet been in actual use.Therefore, in such a situation that material development of a high-kfilm has not yet been completed, the use of a conventional SiO₂ film oran oxynitrided film (SiON) obtained by adding nitrogen to SiO₂ has to beused continuously. That is, thinning the gate insulating film has to befrozen as a matter of practice, or proceeds at a significantly slow paceequal to or lower than approximately 1 angstrom for every several years.Since thinning the gate insulating film has played an extremelyimportant role in pushing forward the scaling, the scaling of siliconsemiconductor technology is in a crisis situation.

Therefore, new device technology developments with no depending onthinning of the gate insulating film have proceed. Since thesetechnologies are not an extension of simple microfabrication, these arecalled technology boosters. Of such technology boosters, the one thatshould be noted is an approach of directly increasing the mobility ofthe silicon transistor. As described above, as the mobility isincreased, the carrier moves faster and, as a matter of course, theprocessing speed of the field-effect transistor becomes faster by thatamount.

One scheme for increasing the mobility is a strained-silicon transistortechnology. The strained-silicon technology is a technology forincreasing the mobility of the carrier by applying a strain to silicon.

Several schemes to apply a strain have been known. For example, in onescheme, by epitaxially growing silicon on silicon germanium epitaxiallygrown on a silicon substrate, tensile strain is applied to silicon, asshown in “J. Welser, Technical Digest of International Electron DeviceMeeting, 1994, pp. 373-376” (Non-Patent Document 1) and “N. Sugii,Technical Digest of International Electron Device Meeting, 2002, pp.737-740” (Non-Patent Document 2). In another known scheme, by depositinga silicon nitride film as a liner film on a field-effect transistor, acompressive or tensile strain is applied to a channel portion, as shownin “F. Ootsuka, Technical Digest of International Electron DeviceMeeting, 2000, pp. 575-578” (Non-Patent Document 3). In still anotherknown scheme, a compressive strain is applied to a channel portion by astrain caused by Shallow Trench Isolation used in device isolation, sothat the hole mobility is increased, as shown in Non-Patent Document 3.In still another known scheme, as shown in “P. Bai, Technical Digest ofInternational Electron Device Meeting, 2004, pp. 657-660” (Non-PatentDocument 4), by epitaxially growing a silicon germanium in vicinity of asource-drain diffusion layer, a compressive strain is selectivelyapplied to a channel portion of a p-type filed-effect transistor inparallel to a channel direction.

As described above, schemes of applying a strain through variousmanufacturing processes have been known. In any of these schemes, themobility is increased to increase a driving current, thereby making itpossible to exchange electrical charge within a shorter time and, as aresult, an increase in processing speed is achieved.

Also, one technological scheme for increasing the driving current of thep-type field-effect transistor without special consideration of themanufacturing method, in which a <100> direction on a (100) substrate istaken as a channel direction, has been known, as shown in “H. Sayama,Technical Digest of International Electron Device Meeting, 1999, pp.657-660” (Non-Patent Document 5).

Also, as technology booster other than that for increasing the drivingcurrent, a scheme using a transistor called FinFET having athree-dimensional structure, has been known, as shown in “D. Hisamoto,Technical Digest of International Electron Device Meeting, 1998, pp.1032-1043” (Non-Patent Document 6). In the FinFET, by taking afinely-divided Silicon On Insulator called Fin as a channel portion, andinterposing the Fin three-dimensionally between a gate insulating filmand a gate electrode, a channel is formed on both sides of the Fin, andas a result, a short-channel effect is suppressed. With the use of theFinFET, further scaling is expected.

SUMMARY OF THE INVENTION

As described above, many suggestions as technologies for furthermicrofabrication and performance enhancement of silicon semiconductortechnologies have been proposed. However, to introduce thesetechnologies, apparatuses with an extremely high price, such as anepitaxial growth apparatus, have to be introduced, so, there is aproblem that an enormous amount of capital investment is required formass production. Therefore, a technology that can achieve performanceenhancement at low cost is desired.

Among the technologies described above, the one achievable at the lowestcost is the technology in which the <100> direction on the (100)substrate is taken as a channel direction. This means that a MOSFET issimply formed in a direction tilted by 45 degrees from a <110> directionnormally used. To perform this, all what is required is to use a waferwith a notch on the (100) substrate oriented in the <100> direction.Since using such a wafer is easy, this technology has already been usedat mass production sites.

However, as a matter of fact, the reason why the driving current isincreased by using the <100> direction has not yet been academicallyclarified. Normally, an increase in driving current means an increase inmobility. However, it has been reported that the results of measurementof the mobility in the <100> direction in a MOSFET with a large channellength are identical to those in the <110> direction, in “H. Irie and A.Toriumi, Solid State Devices and Materials, 2004, pp. 724-725”(Non-Patent Document 7). Therefore, in at least the MOSFET with a largechannel length, it has been revealed that the mobility in the <100>direction is approximately equal to the mobility in the <110> direction.

For device designing optimal for the driving current of the pMOSFET, theabove-mentioned question has to be answered. Also, if the answer isobtained, more optimal device design for increasing the driving currentof the pMOSFET at low cost is realized.

In addition, to improve the performance of the LSI, only improving theperformance of the pMOSFET is insufficient. In modern LSIs, circuit isoften configured with a CMOS (Complementary MOS), therefore, theperformance of the nMOSFET has to be improved at the same time.

An object of the present invention is to provide a semiconductor deviceand its manufacturing method in which the driving current of a pMOSFETis increased with easily-formable scheme using existing silicon process.

First, a question why the driving current of the pMOSFET is increasedonly in a device with a short channel length but not in a device with along channel length, is solved.

To solve this question, a MOSFET as shown in FIG. 1 was formed on asilicon substrate 1 with a normal (100) surface as a plane direction ofa surface. The silicon substrate 1 used is based on normalspecifications with a notch 2 being in a <110> direction for easiness ofdicing a chip. Here, a crystal face and a direction are additionallydescribed. In the present invention, a notation “the (100) surface” isnot differentiated from equivalent surfaces, such as (010) and (001)surfaces, based on normal crystallographic classification. Similarly,the <100> direction is equivalent to the <010> and <001>. Also, it isneedless to say, <110> is equivalent to <011> and <101>.

In the case where this (100) substrate with the <110> notch 2 is used, adevice normally formed is a MOSFET in which the direction of a currentflowing from a source diffusion layer 3 to a drain diffusion layer 4 isparallel to the <110> direction. This device is hereinafter referred toas a <110> channel device. In the <110> channel device, a channel lengthL is defined by a gate electrode 5. And, the channel width is defined bya width W of the source diffusion layer 3 and the drain diffusion layer4. On a surface portion of the substrate 1 where no device exists, aninsulator formed through Shallow Trench Isolation is buried, which is anormal configuration.

In addition to this <110> channel device, a MOSFET in a direction inwhich the <110> channel device is rotated by 45 degrees is formed. Thatis, in this MOSFET, the direction of the current flowing from a sourcediffusion layer 6 to a drain diffusion layer 7 is parallel to the <100>direction. In this <100> channel device, a gate electrode 8 is alsooriented to a direction rotated by 45 degrees.

By forming the <110> channel device and the <100> channel device on thesame substrate 1 in this manner, both devices can be compared withexactly the same manufacturing process. Also, although not shown in FIG.1 for simplification, by forming a plurality of devices with differentchannel lengths L and channel widths W, difference between along-channel device and a short-channel device can be clarified.

As a result, electrical characteristics as shown in FIG. 2 wereobtained. On the left side of FIG. 2, a drain current-gate voltagecharacteristic of a short-channel device with L=0.12 μm is shown, and agraph inserted therein shows results plotted on a log scale. From thesecharacteristics, it was confirmed that the current flowing in the <100>channel device is larger than that in the <110> channel device by 19%.This attests the conventional knowledge shown in Non-Patent Document 5,that is, as for the short-channel device, a larger driving current canbe obtained from the <100> channel device than the <110> channel device.

On the other hand, in a mobility characteristic of a long-channel devicewith L=20 μm shown on the right side of FIG. 2, the difference betweenthe <100> channel device and the <110> channel device is merely asslight as 5%. This attests the conventional knowledge shown inNon-Patent Document 7, that is, as for the long-channel device, thedifference of a mobility between the <100> channel device and the <110>channel device is small.

Normally, if the channel length becomes shorter, influences of externalresistance and velocity saturation become significant, and therefore thedifference in driving current due to the difference in mobility israther decreased. Therefore, such a difference as described abovebetween the short-channel device and the long-channel device isextremely abnormal.

To find out a physical reason of this phenomenon, following points wereexamined. That is, if superiority of the <100> channel device occursonly in the short-channel device but no significant difference occurs inthe long-channel device, either one of the following two should occur:(1) an exotic new physical phenomenon that is not noticeable until thechannel length is shortened; and (2) there is a cause for increasing themobility when the channel length is shortened.

As for (1), no specific example academically accepted is present.Therefore, if the possibility of (2) cannot be denied, a proposal of (1)cannot be accepted. Therefore, the possibility of (2) was considered.That is, the possibility that the mobility of the short-channel deviceis different from the mobility of the long-channel device wasconsidered.

In exploring the cause of change in the mobility due to a decrease inchannel length, it was found that as the channel length is shortened, adistance from an end of the source diffusion layer 3 or 6 to an end ofthe drain diffusion layer 4 or 7 is shortened. To make this point clear,a <100> channel device with a long channel is shown in FIG. 3. In FIG.3, a distance represented by “d” corresponds to a distance from an STIadjacent to the end of a source diffusion layer 6 to an STI adjacent tothe end of a drain diffusion layer 7. Although not shown, it is needlessto say that the same goes for a <110> channel device. As the distance dbetween STIs is decreased, a compressive strain stress applied to thechannel portion existing immediately under the gate electrode 8 ispossibly increased. It is understandable that the mobility is increasedwith an increase in compressive strain.

However, in the conventional strain measuring apparatus, it is difficultto find a strain of the device in a nondestructive state. In destructivemeasurement in which a device is finely cut out, a strain is changedwhen the device is taken out, therefore, a subtle difference in straincannot be detected. Therefore, a Raman measurement with an extremelyhigh measurement sensitivity is performed.

The results are shown in FIG. 4. As the channel length is shortened, aRaman shift is increased. Thus, it was revealed for the first time thata compressive strain is increased indeed. It was also revealed that thedrain current of the <100> channel device is larger than the current ofthe <110> channel device. That is, it was revealed for the first timethat, as for the short channel, the reason for a larger driving currentof the <100> channel device than that of the <110> channel device is anincrease in mobility due to a difference in compressive strain appliedby STI.

By this new matter, the importance of the compressive strain isre-recognized. And developments for a scheme for applying a compressivestress better than currently-known schemes have been done.

As one scheme of increasing the mobility of a pMOSFET, a method in whicha one-axis compressive strain is applied in a direction parallel to thechannel, as shown in Non-Patent Document 4, is known.

The reverse method, that is, a scheme of applying a one-axis compressivestrain in a direction perpendicular to the channel, is tried. To dothis, all what is required is to examine the mobility of a device with anarrow channel width W. However, it is usually difficult to measure themobility if the channel width is narrow. Because, if the channel widthis narrow, an effective region of the channel portion is decreased,thereby making it impossible to measure a capacitance.

To solve this problem, a device with a multi-channel configuration inwhich a plurality of channels with a narrow channel width W are coupledtogether as shown in FIG. 5 is formed. In FIG. 5, an example of amulti-channel MOSFET formed using a (100) substrate 11 having a notch 12in the <100> direction is shown. The multi-channel MOSFET in FIG. 5 hasfive channels interposed by four STI units 16 under a gate electrode 15.

FIG. 6 shows the mobility of the device formed. For W=10 μm, an exampleof a normal pMOSFET with one channel is shown. On the other hand, forW=1 μm, a pMOSFET with ten channels, and for W=0.25 μm, a pMOSFET with40 channels is formed respectively, so that a total of the effectivewidths of the each devices was adjusted to equal to 10 μm. Thus, aprecise measurement of the mobility is realized for the first time.

As a result, it was revealed for the first time that, as for the <110>channel device, the mobility is hardly changed with an one-axiscompressive strain being applied to a direction perpendicular to thechannel as shown on the left side of FIG. 6, on the other hand, as forthe <100> channel device, the mobility is increased as shown on theright side of FIG. 6. In particular, it was revealed that, although thecompressive strain applied was on the order of 300 MPa, which is not sostrong, an overwhelming effect was obtained such that the increment ofmobility by approximately 30%.

Furthermore, as shown in FIG. 7, short-channel devices with differentchannel widths were formed to examine the driving current. As a result,it was demonstrated that an increase in driving current by as much as65% at the maximum is available.

Therefore, it is revealed that, in order to increase the mobility of thepMOSFET, applying a compressive strain in a direction perpendicular tothe channel is quite effective.

Based on these matters, a method of increasing the driving current ofthe pMOSFET is specifically disclosed in the following. In addition to amulti-channel MOSFET, a method of increasing the mobility by applying astrain to a FinFET is also disclosed. Furthermore, a scheme ofincreasing the driving current of an nMOSFET is disclosed at the sametime.

According to the present invention, by using the existing semiconductormanufacturing apparatus without special capital investment, the drivingcurrent of the pMOSFET can be increased. Therefore, an LSI capable ofhigh-speed processing at low cost can be provided.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic view of a short-channel device for explaining anexperiment on which the present invention is based;

FIG. 2 shows experiment data on which the present invention is based;

FIG. 3 is a schematic view of a long-channel device for explaining anexperiment on which the present invention is based;

FIG. 4 shows experiment data on which the present invention is based;

FIG. 5 is a schematic view of a transistor according to the firstembodiment of the present invention;

FIG. 6 shows experiment data on which the present invention is based;

FIG. 7 shows results of improvement of transistor characteristicaccording to the first embodiment of the present invention;

FIG. 8A is a cross-section view for depicting a transistor manufacturingprocess according to the first embodiment of the present invention;

FIG. 8B is a cross-section view for depicting a transistor manufacturingprocess according to the first embodiment of the present invention;

FIG. 8C is a cross-section view for depicting a transistor manufacturingprocess according to the first embodiment of the present invention;

FIG. 8D is a cross-section view for depicting a transistor manufacturingprocess according to the first embodiment of the present invention;

FIG. 9A is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 9B is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 9C is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 9D is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 10A is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 10B is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 10C is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 10D is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 11A is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 11B is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 12A is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 12B is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 13A is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 13B is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 13C is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 13D is a cross-section view for depicting the transistormanufacturing process according to the first embodiment of the presentinvention;

FIG. 14A is a cross-section view for depicting a transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 14B is a cross-section view for depicting a transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 14C is a cross-section view for depicting a transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 15A is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 15B is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 16A is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 16B is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 17A is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 17B is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 17C is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 18A is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 18B is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 18C is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 19A is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 19B is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 20A is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 20B is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 21A is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 21B is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 22A is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 22B is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 23A is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 23B is a cross-section view for depicting the transistormanufacturing process according to the second embodiment of the presentinvention;

FIG. 24A is a cross-section view for depicting a transistormanufacturing process according to the third embodiment of the presentinvention;

FIG. 24B is a cross-section view for depicting a transistormanufacturing process according to the third embodiment of the presentinvention;

FIG. 25A is a cross-section view for depicting the transistormanufacturing process according to the third embodiment of the presentinvention;

FIG. 25B is a cross-section view for depicting the transistormanufacturing process according to the third embodiment of the presentinvention;

FIG. 25C is a cross-section view for depicting the transistormanufacturing process according to the third embodiment of the presentinvention;

FIG. 26A is a cross-section view for depicting the transistormanufacturing process according to the third embodiment of the presentinvention;

FIG. 26B is a cross-section view for depicting the transistormanufacturing process according to the third embodiment of the presentinvention;

FIG. 27A is a cross-section view for depicting a transistormanufacturing process according to the fourth embodiment of the presentinvention;

FIG. 27B is a cross-section view for depicting a transistormanufacturing process according to the fourth embodiment of the presentinvention;

FIG. 27C is a cross-section view for depicting a transistormanufacturing process according to the fourth embodiment of the presentinvention;

FIG. 27D is a cross-section view for depicting a transistormanufacturing process according to the fourth embodiment of the presentinvention;

FIG. 27E is a cross-section view for depicting a transistormanufacturing process according to the fourth embodiment of the presentinvention;

FIG. 28A is a cross-section view for depicting the transistormanufacturing process according to the fourth embodiment of the presentinvention;

FIG. 28B is a cross-section view for depicting the transistormanufacturing process according to the fourth embodiment of the presentinvention;

FIG. 28C is a cross-section view for depicting the transistormanufacturing process according to the fourth embodiment of the presentinvention;

FIG. 29 is a mask layout depicting an inverter arrangement according tothe first embodiment of the present invention;

FIG. 30 is a mask layout depicting another inverter arrangementaccording to the first embodiment of the present invention; and

FIG. 31 is a mask layout depicting an NAND gate arrangement according tothe first embodiment of the present invention.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Embodiments of the present invention are described in detail below basedon the drawings. Here, in the drawings for description of theembodiments, components having the same function are provided with thesame symbols, and are not repeatedly described herein. Also, it isneedless to say that, other than the methods introduced in theembodiments, various changes are possible by, for example, changingcombinations of materials and manufacturing processes.

First Embodiment

In a first embodiment, a method of manufacturing a multi-channel pMOSFEThaving a channel in a <100> direction on a (100) substrate and capableof achieving a high mobility by applying a compressive distortionthrough an STI from a direction perpendicular to a channel is disclosed.FIG. 5 is a drawing of this device viewed from the top.

FIGS. 8A to 8D show a manufacturing process using sectional views alonga section 17 in FIG. 5. FIGS. 9A to 9D show a manufacturing processusing sectional views along a section 19 in FIG. 5. The process isdescribed below in sequence.

First, a (100) substrate 11 having a notch 12 in a <100> direction isprovided. As the (100) substrate 11, a substrate formed only of singlecrystal silicon, or an SOI substrate may be used. In a case where an SOIsubstrate is used, the SOI layer having a (100) surface with a notch 12in the <100> direction can be used. Also, even if a normallymass-produced <100> substrate having the notch 12 oriented not in the<100> direction but in the <110> direction is used, it is needless tosay that effects exactly the same as the following effects can beexpected when the device itself is formed as being rotated by 45degrees.

Next, the surface of the substrate 11 is oxidized to form a siliconoxide film 21 having a film thickness on the order of 100 nm on itssurface. Then, a silicon nitride film 22 is deposited on the order of100 nm to bring about a state shown in FIG. 8A and FIG. 9A.

Then, to process a desired region where an STI is to be formed,photolithography and dry etching are used to process a part of thesilicon nitride film 22, thereby bringing about a state shown in FIG. 8Band FIG. 9B.

Next, a part of the silicon oxide film 21 and a part of the siliconsubstrate 11 are removed through dry etching, thereby bringing about astate shown in FIG. 8C and FIG. 9C.

Next, after a silicon oxide film is deposited all over the entiresurface, the surface is planarized through Chemical MechanicalPolishing, and then silicon nitride film 22 and the silicon oxide film21 are removed through wet etching, thereby bringing about a state shownin FIG. 8D and FIG. 9D where a buried insulating film 23 is formed. Bythis process, an STI is completed.

Here, as describe above, a deposited film of silicon dioxide for use ina normal silicon process can be used as the buried insulating film 23.If the mobility is further increased by particularly intensifying acompressive stress to be applied to the channel portion, it is effectiveto perform an oxidizing process after silicon buried once. In the lattercase, the fact that a volume of the silicon is expanded to beapproximately doubled at an oxidizing reaction of silicon to silicondioxide is used, therefore, a more strong compressive strain can beapplied. Also, by using a silicon nitride film as the buried insulatingfilm 23, in place of a silicon oxide film, a stress control using aninternal strain included in the silicon nitride film become possible.

Furthermore, another device isolation scheme may be performed in which,in the state in FIG. 8C and FIG. 9C, silicon is deposited after adeposition of silicon nitride, then, silicon in an NMOS formation region(not shown) is removed through photolithography and dry etching, afterthat, an oxidizing process is performed to the silicon deposited in aPMOS formation region to generate silicon dioxide; and then, after asilicon oxide film is further deposited on the entire surface, thesilicon nitride film 22 and the silicon oxide film 21 are removedthrough chemical-mechanical polishing and wet etching. In this case, theburied insulating film 23 has a multilayered structure of the siliconnitride film and the silicon oxide film. As a result, a very strongcompressive stress can be applied to the PMOS formation region, while nocompressive stress is applied to the NMOS formation region. Furthermore,by controlling the stress of the silicon nitride film, even a tensilestress can be applied to the NMOS formation region.

In this manner, with variations on the buried insulating film 23,various stresses can be applied to a desired region.

Next, a method of forming a multi-channel pMOSFET in an active regiondevise-isolated by the formed STI is described.

FIGS. 10A to 10D and FIGS. 11A and 11B show a manufacturing processusing sectional views along the section 17 in FIG. 5. FIGS. 12A to 12Bshow a manufacturing process using sectional views along a section 18 inFIG. 5. FIGS. 13A to 13D show a manufacturing process using sectionalviews along a section 19 in FIG. 5. The process is described below insequence.

First, the surface of the substrate 11 is subjected to a cleaningprocess for cleaning. Then, a gate insulating film 24 is formed. As thegate insulating film 24, whether silicon dioxide formed by oxidizing thesurface of the silicon substrate, a silicon oxynitride film subjected toa nitriding process, or a high-dielectric-constant gate insulating filmwith a larger relative dielectric constant can be used. In the presentembodiment, a silicon dioxide film having a film thickness of 2.5 nm isused as the gate insulating film. Then, a polycrystalline silicon gateelectrode 15 is deposited on the entire surface, thereby bringing abouta state shown in FIGS. 10A, 12A, and 13A.

Then, by using photolithography and dry etching, the polycrystallinesilicon gate electrode 15 is processed to a desired shape, therebybringing about a state shown in FIG. 10B.

Next, shallow ion implantation is performed on the PMOS formationregion. Then, after an appropriate time is elapsed, activating annealingis performed at 1000° C., and a source diffusion layer 13 and a draindiffusion layer 14 are formed, thereby bringing about a state shown inFIG. 10C and FIG. 13B.

Next, after a silicon oxide film is deposited on the entire surface,anisotropic dry etching is performed. With this, the silicon oxide filmis selectively left only on side walls of the polycrystalline silicongate electrode 15 to form side walls 25, thereby bringing about a stateshown in FIGS. 10D and 13C.

Next, in order to perform a SALICIDE (Self-Aligned-siLICIDE) process, aNi film is deposited thinly on the entire surface through spattering,then, siliciding through annealing is performed, and then a non-reactedportion of the Ni film is removed through a wet process to left a Nisilicide film selectively on a silicon-exposed portion. Then, a Nisilicide film 26 is subjected to a resistance-reduce process through ashort-time heat treatment, thereby bringing about a state shown in FIG.11A and FIG. 12B to form a p-type multi-channel MOSFET. In the SALICIDEprocess, in place of Ni, another metal material, such as Co, can beused. Then, after an interlayer film 27 is deposited on the entiresurface, the surface is planarized through chemical-mechanicalpolishing. Then, desire openings are formed to fabricate wiring metals28, thereby bringing about a state shown in FIG. 11B. If morecomplicated wirings are required, a wiring process can be performed aplurality of times.

In the characteristic of thus formed device, the driving current issignificantly increased by 65% at the maximum compared with theconventional driving current, as shown in FIG. 7. Effects of such anextremely large driving current far exceed a restriction in layout thatthe transistors with a thin channel width have to be coupled together.In fact, a switching speed of a transistor is often represented by CV/Iwhere C is a capacitance, V is a voltage, and I is a driving current,and it does not depend on the channel width W. Therefore, it can be saidthat the increase in driving current of 65% due to the increase inmobility directly provides an improvement in switching speed.

A current ULSI is configured with a CMOS inverter as a basic gate. Thisis because the CMOS inverter includes an NMOS and a PMOS operating in acomplementary manner, therefore, operations can be performed with anextremely low power. An CMOS inverter, which is basic element, isconfigured by one NMOS and one PMOS. However, since the NMOS and thePMOS have different current driving powers, the gate width of the PMOSis set longer than that of the NMOS, that is, doubled, so as to obtainan equal current driving power. According to the present invention, byforming a PMOS with a multi-channel PMOS, a large current driving powercan be obtained. So, to widen the gate width, it is effective to dividethe PMOS into plural in layout, as shown in FIG. 29. Also, by dividingthe gate of the PMOS as shown in FIG. 30 to form a multi-channel, thetotal gate width can be increased. In this case, by taking a diffusionlayer interposed by the divided gates as a drain side, the draindiffusion layer can be decreased and a parasitic capacitance can bereduced. An example in which the present invention is applied to a NANDgate with two CMOS inverters combined together is shown in FIG. 31. Inthe drawing, portion laid out in squares represent contacts. Contactswith crossed lines in the square represent contacts to a power supplyand a ground wiring, and contacts with a diagonal line from upper rightto left below represent contacts serving as output terminals.Furthermore, contacts each with a diagonal line from upper left to lowerright represent contacts to a gate electrode.

Second Embodiment

In a second embodiment, based on the knowledge, leading to the presentinvention, as for the <100> channel, by applying a compressive strain ina direction perpendicular to the channel, the mobility of the pMOSFET isincreased, a method of increasing the mobility in a multi-channelFin-type FET is disclosed. The FinFET has a self-aligned-typedouble-gate configuration in which a side wall portion of an SOI formedin a fin shape like a shark's dorsal fine is taken as a channel.Therefore, as for the pMOSFET, it can be recognized easily that a stresspressing the fin from above is effective. In the present embodiment, amethod of achieving the above with a film stress of a silicon nitridefilm is disclosed. And, for a CMOS operation, an increase in drivingcurrent of an NMOS is indispensable. As for the NMOS, two-dimensionallystraining the side surfaces of the fin is most effective in increasingthe mobility. Therefore, a strong tensile strain exceeding a compressivestrain applied to the PMOS has to be applied. In the present embodiment,a method is disclosed in which, in the multi-fin configuration, afterfilling silicon among a plurality of fins, an oxidizing process isperformed, so that the side walls of the fin are pressed extremely hardto apply a tensile stress in a fin plane.

FIGS. 14A to 14C, FIGS. 15A and 15B, and FIGS. 16A to 16B are schematicdrawings viewed from a section of the channel portion of themulti-channel FinFET to show a manufacturing process based on thepresent embodiment. Also, FIGS. 17A to 17C, FIGS. 18A to 14C, and FIGS.19A and 19B are schematic drawings viewed from a section on the gate toshow the manufacturing process. Furthermore, FIGS. 20A and 20B, FIGS.21A and 21B, FIGS. 22A and 22B, and FIGS. 23A and 23B are schematicdrawings viewed from an upper side of the substrate to show themanufacturing process. The process is described below in sequence.

Firstly, a (100) SOI substrate having a notch 12 in a <100> direction isprovided. This SOI substrate have a BOX layer (Buried Oxide layer, aburied oxide film layer) 31 as a supporting substrate formed onsingle-crystal silicon substrate 30, and furthermore, SOI layer having anotch 12 in the <100> direction is formed on BOX layer 31, as shown inFIG. 14A, FIG. 17A, and FIG. 20A. To manufacture this SOI substrate, alaminating scheme or a SIMOX (Separation by IMplanted OXygen) scheme maybe taken. With such a substrate, all the side walls and the uppersurface of the fin can be the (100) surfaces. Such (100) surfaces havethe highest electron mobility, and in addition, by controlling the <100>direction and the compressive strain, hole mobility can be increased.

Next, the SOI layer 32 is processed in a fin shape throughphotolithography and dry etching, thereby bringing about a state shownin FIG. 14B, FIG. 17B, and FIG. 20B. Here, fins at both ends of a PMOSshown in FIG. 17B and an NMOS shown in FIG. 20B are inserted as dummiesso as to ensure the stability of the configuration even underapplication of a strain. Therefore, although a multi-Fin FET havingthree channels is shown in the drawings of the present embodiment, noproblem occurs even if the number of fins may be more or less.

Next, after the surface is subjected to a cleaning process for cleaning,a gate insulating film 33 is formed. As the gate insulating film 33,silicon dioxide formed by oxidizing the surface of the siliconsubstrate, a silicon oxynitride film subjected to a nitriding process,or a high-dielectric-constant gate insulating film with a largerrelative dielectric constant can be used. In the present embodiment, asilicon dioxide film having a film thickness of 2.0 nm is used as thegate insulating film. Then, a polycrystalline silicon gate electrode of30 nm and a silicon dioxide hard mask of 100 nm are deposited on theentire surface and to processed through photolithography and dry etchinginto a PMOS polycrystalline silicon gate electrode 34, an NMOSpolycrystalline silicon gate electrode 35, and a silicon dioxide hardmask 36, thereby bringing about a state shown in FIGS. 14C, 17C, and21A.

Next, using a resist mask, B is ion-implanted in a PMOS region, and P ision-implanted in an NMOS region. Then, after an appropriate time iselapsed, activating annealing is performed at 1000° C., and then asource diffusion layer 37 and a drain diffusion layer 38 are formed onthe PMOS region, and a source diffusion layer 39 and a drain diffusionlayer 40 are formed on the NMOS region, thereby bringing about a stateshown in FIG. 15A.

Note that, the fins at both ends used as dummies are, in an electricalsense, not directly connected to the source diffusion layers 37 and 39and the drain diffusion layers 38 and 40. Therefore, a current does notflow directly, but capacitive coupling exists. At ion implantation, ionimplantation may be performed on the fins at both ends used as dummies,but the parasitic capacitance is preferably as small as possible.

Next, after the silicon dioxide hard mask 36 is removed through dryetching, silicon dioxide is deposited on the entire surface, andanisotropic dry etching performed so as to form side walls 41 depositedon side walls of the PMOS polycrystalline silicon gate electrode 34, andthe NMOS polycrystalline silicon gate electrode 35, thereby bringingabout a state shown in FIG. 15B, FIG. 18A, and FIG. 21B.

Next, a Ni film is thinly deposited on the entire surface throughspattering, and siliciding through annealing is performed, and thennon-reacted portion of the Ni film is removed through a wet process toleft a silicide film selectively on a silicon-exposed portion. Then, aNi silicide film is subjected to a resistance-reduce process through ashort-time heat treatment to form a PMOS complete silicide gateelectrode 43, an NMOS complete silicide gate electrode 44, and diffusionlayer silicide 42, thereby bringing about a state shown in FIG. 16A,FIG. 18B, and FIG. 22A.

Next, a silicon nitride film 45 having a tensile strain is deposited onthe entire surface to bring about a state shown in FIG. 16B, FIG. 18Cand FIG. 22B, in which a compressive stress to press the FinFET on thesubstrate side is applied. Such a stress increases hole mobility of atransistor in the PMOS region. That is, in a conventionally-known stressapplying scheme, a film providing a tensile stress is deposited in orderto increase the mobility of the NMOS. However, in this scheme, themobility of the PMOS is decreased. Therefore, on the PMOS, a methodforming a film without a tensile stress or a film providing acompressive stress conversely is available. However, in a fin-channelMOS according to the present invention, it becomes possible to deposit afilm having a tensile stress on both of the NMOS and the PMOS.

Next, a process for increasing the mobility of the NMOS is performed.After silicon is deposited on the entire surface, by patterning to adesired shape using a resist mask, silicon in the PMOS region is removedthrough dry etching. After an appropriated time is elapsed,chemical-mechanical polishing is performed, strain-applying silicon 46is selectively buried in a space between the silicon nitride films 45 onan upper portion of the NMOS complete silicide gate electrode 44,thereby bringing about a state shown in FIG. 19A and FIG. 23A. Notethat, in FIGS. 23A and 23B, for easy understanding, the silicon nitridefilm 45 is not shown. And, the crystalline state of the strain-applyingsilicon 46 may be an amorphous state or a polycrystalline state.

Then, an oxidizing process is performed to change the strain-applyingsilicon 46 to strain-applying silicon dioxide 47, thereby bringing abouta state in FIGS. 19B and 23B. As described above, the volume of siliconis doubled through oxidization, and therefore a strong stress is appliedto the side walls of the fin. Since this stress is larger than a stressformed by the silicon nitride film 45, an effective tensile stress isapplied to the side walls of the fin in the NMOS formation region.Thereafter, a desired wiring process is performed to manufacture amulti-channel FinFET.

The multi-channel FinFET manufactured in this manner, both of the PMOSand NMOS have a mobility larger than that of the normal MOSFET withoutstrain application formed on the (100) surface by 50% or more. Thus, thescheme of effectively applying a strain to the multi-channel FinFET isrevealed.

Third Embodiment

In the present embodiment, a method for manufacturing a multi-channelfin-type FET in which, in forming a complete silicide gate electrode, astress is applied using the fact that the volume of the gate electrodeis expanded, is disclosed. Also in the present embodiment, the mobilityof the PMOS and the mobility of the NMOS can be increased at the sametime.

FIGS. 24A and 24B are schematic drawings viewed from a section of thechannel portion of the multi-channel FinFET showing a manufacturingprocess based on the present embodiment. And, FIGS. 25A to 25C areschematic drawings viewed from a section on the gate to show themanufacturing process. And, FIGS. 26A and 26B are schematic drawingsviewed from an upper side of the substrate to show the manufacturingprocess. The process is described below in sequence.

Firstly, the state shown in FIG. 15B, FIG. 18A, and FIG. 21B where theside walls 41 have been formed are brought about through the methodaccording to the second embodiment.

Next, after a silicon nitride film is deposited on the entire surface,by patterning to a desired shape using a resist mask, the siliconnitride film in the PMOS region is removed through dry etching. After anappropriate time is elapsed, chemical-mechanical polishing is performedto selectively bury a silicon nitride film for strain application 50 ina space between the side walls 41 of the NMOS, thereby bringing about astate shown in FIG. 25A and FIG. 26A.

Next, a Ni film 51 is thinly deposited on the entire surface throughspattering. After an appropriate time is elapsed, a silicon nitride film52 is deposited on the entire surface. Then, with patterning usingphotolithography, the silicon nitride film 52 is left only in the PMOSformation region, thereby bringing about a state shown in FIG. 24A andFIG. 25B.

Then, siliciding through annealing is performed so that a Ni silicidefilm is left selectively on a silicon-exposed portion. In forming Nisilicide, the volume of the PMOS polycrystalline silicon gate electrode34 is expanded. At this time, its upper portion is pressed by thesilicon nitride film 52, and therefore a compressive strain is appliedfrom the top to the bottom of the substrate to press the fin onto thesubstrate. Therefore, the mobility of the PMOS is increased. On theother hand, since no silicon nitride film 52 exists in the NMOSformation region, such a compressive stress is not applied. Instead,since the silicon nitride film for strain application 50 is buried, Nisilicide is formed, and repulsion occurs between adjacent side walls onthe fin side according to the expansion of the volume of the NMOSpolycrystalline silicon gate electrode 35. As with the secondembodiment, this acts in a tensile direction on the side walls of thefin, therefore, mobility of the NMOS is increased. After Ni silicide iscompletely formed, the silicon nitride film 52 is removed. Then, anon-reacted portion of the Ni film is removed through a wet process,thereby bringing about a state shown in FIG. 24B, FIG. 25C and FIG. 26B.

Thereafter, a desired wiring process is performed so that amulti-channel FinFET is manufactured.

In thus manufactured multi-channel FinFET, both of the PMOS and NMOShave an increase in mobility approximately equivalent to the secondembodiment. The number of processes can be slightly reduced comparedwith the method according to the third embodiment. And, the methodaccording to the second embodiment and the method according to the thirdembodiment can be easily combined to apply a larger strain. Thus, thescheme of effectively applying a strain to the multi-channel FinFET hasbeen revealed.

Fourth Embodiment

The manufacturing methods according to the second embodiment and thethird embodiment are aimed at application to a multi-channel FinFET, aMOSFET of the next generation. Under the current circumstances, using aSOI substrate increases cost because the wafer is expensive. On theother hand, in the course of manufacturing described above, a methodthat can be readily applied to a current planar-type MOSFET is revealed.

In the present embodiment, a new method of applying a strain to a normalplanar-type MOSFET is described. FIGS. 27A to 27D are drawings to show aprocess of manufacturing a STI portion.

Firstly, a normal (100) silicon substrate 61 is provided. Since thenotch direction is not be restricted to the <100> direction in thepresent embodiment, a normally-used substrate having a notch oriented toa <110> direction is used.

Other than the substrate used in the present embodiment, a SOI substrateor a Strained Silicon On Insulator (SSOI) substrate, which has strain,can be used. And, in the case where no problem with manufacturing costexists and an SSOI is used, since the mobility of the NMOS is increased,and by using the method according to the present embodiment, themobility of the PMOS is also sufficiently increased, therefore, theperformance can be increased mostly.

Next, an oxidizing process is performed on the surface of the (100)substrate 61 to form a silicon oxide film 62 having a film thickness onthe order of 100 nm on the surface. Then, a silicon nitride film 63 isdeposited so as to have a film thickness on the order of 100 nm, therebybringing about a state shown in FIG. 27A.

Next, to process a desired region where an STI is formed,photolithography and dry etching are used to process a part of thesilicon nitride film 63, thereby bringing about a state shown in FIG.27B.

Then, a part of the silicon oxide film 62 and a part of the siliconsubstrate 61 are removed through dry etching, thereby bringing about astate shown in FIG. 27C.

Next, after depositing a silicon oxide film 64 thinly on the entiresurface, silicon 65 is thinly deposited. The crystalline state ofsilicon may be an amorphous state or a polycrystalline silicon state. Inthe present embodiment, amorphous silicon is used. Then, usingpatterning through photolithography, the silicon 65 deposited in theNMOS formation region is removed. Then, after depositing a silicon oxidefilm 66 on the entire surface, the surface is planarized throughchemical-mechanical polishing, thereby bringing about a state shown inFIG. 27D. Here, in the NMOS formation region, a silicon oxide film 67formed as a multilayered film of the silicon oxide film 64 and thesilicon oxide film 66 is buried.

Next, a thermal oxidizing process is performed to oxidize the silicon65, therefore, a buried insulating film 68 is formed in the PMOSformation region. Here, in this thermal oxidizing process, since anextremely strong strain stress is applied to the silicon 65, anoxidizing rate is slowed. Therefore, some silicon in the buriedinsulating film 68 may be left not completely oxidized. Then, thesilicon nitride film 63 and the silicon oxide film 62 are removedthrough wet etching, thereby bringing about a state shown in FIG. 27E.

By forming an STI in this manner, a compressive strain can beselectively applied to an active region of the PMOS formation region.The direction of the compressive strain can be in parallel orperpendicular to the channel.

Then, through a normal CMOS process disclosed in the first embodiment, atransistor is formed. On the other hand, as for the NMOS, a stress isnot sufficiently applied, therefore, the following method is disclosedin the present embodiment.

FIGS. 28A to 28C show a manufacturing process.

Firstly, an NMOS transistor is formed through processes similar to thoseaccording to the first embodiment so as to form a configuration in whicha gate insulating film 70, a polycrystalline silicon gate electrode 71,a source diffusion layer 72, a drain diffusion layer 73 and side walls74 are formed on the active region defied by the silicon oxide film 67,as shown in FIG. 28A.

Next, a Ni film 75 is thinly deposited on the entire surface throughspattering. After an appropriate time is elapsed, a silicon nitride film76 is deposited on the entire surface. Then, through patterning usingphotolithography, the silicon nitride film 76 is left only in the NMOSformation region, thereby bringing about a state shown in FIG. 27B.

Then, siliciding through annealing is performed to left a Ni silicidefilm selectively on a silicon-exposed portion. By formation of Nisilicide, the volume of the polycrystalline silicon gate electrode 71 isexpanded. At this time, since its upper portion is pressed by thesilicon nitride film 76, a compressive strain is applied from the top tothe bottom of the substrate in a direction to press the polycrystallinesilicon gate electrode 71 onto the substrate. Therefore, a tensilestress is applied to the channel portion, therefore, the mobility of theNMOS is increased. On the other hand, in the PMOS formation region, nosilicon nitride film 76 exists, so, such a compressive stress is notapplied.

After Ni silicide is completely formed, the silicon nitride film 76 isremoved. After that, a non-reacted portion of the Ni film is removedthrough a wet process, thereby bringing about a state shown in FIG. 27C.

Thereafter, a desired wiring process is performed, as a result, a devicewith a high mobility of both of the NMOS and the PMOS is manufacturedinexpensively.

1. A semiconductor device including a p-type field-effect transistor,comprising: a formation region of the p-type field-effect transistor,surrounded by a first STI, and formed of a semiconductor substrate witha plane direction of a surface being a (100) surface; a second STIsurrounded by the formation region of the p-type field-effect transistorand separated from the first STI; and a gate electrode provided so as torun upon the second STI, and to cross the formation region of the p-typefield-effect transistor in a <010> direction, wherein a direction of achannel formed on a surface of the formation region of the p-typefield-effect transistor under the gate electrode is set as a <100>direction.
 2. A semiconductor device including a MOS inverter, wherein ap-type field-effect transistor forming a CMOS inverter comprises: aformation region of the p-type field-effect transistor surrounded by afirst STI and formed of a semiconductor substrate with a plane directionof a surface being a (100) surface; a second STI surrounded by theformation region of the p-type field-effect transistor and separatedfrom the first STI; and a gate electrode provided so as to run upon thesecond STI, and to cross the formation region of the p-type field-effecttransistor in a <010> direction, and wherein a direction of a channelformed on a surface of the formation region of the p-type field.effecttransistor under the gate electrode is set as a <100> direction.